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Concise Synthesis of Acyl Migration-Blocked 1,1-Difluorinated Analogues of Lysophosphatidic Acid

โœ Scribed by Xu, Yong; Prestwich, Glenn D.

Book ID
127383162
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
91 KB
Volume
67
Category
Article
ISSN
0022-3263

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โœ Jollie D Godfrey Jr.; Richard H Mueller; Derek J Von Langen ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 218 KB

The cyclization of hydroxamate 1 unexpectedly afforded two isomeric @lactams 2 and 1. The mechanism for the formation of 2 has been shown by carbon-13 labeling to involve a novel 1,2-acyl migration-cyclization process.