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Concerning the mechanism of the reductive cleavage of α-nitrocumene and cumyl chloride

✍ Scribed by Donald B. Denney; Dorothy Z. Denney; Steven P. Fenelli

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 280 KB
Volume: 53
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(97)00258-5

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✦ Synopsis

The reductive cleavages of cx-nitrocumene and cumyl chloride by sodium naphthalenide in tetrahydrofuran have been studied. It is concluded that the cumyl carbanion is the first intermediate fi~rmed in these reactions.

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