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On the mechanism of the reductive cleavage of anti-9-phenyl-cis-bicyclo[6.1.0]nona-2,4,6-triene

✍ Scribed by S.W. Staley; G.E. Linkowski; A.S. Heyn


Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
315 KB
Volume
31
Category
Article
ISSN
0040-4020

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Reaction of cis-Bicyclo[6.1.0]nona-2,4,6
✍ Dr. Gernot Boche; Dipl.-Chem. Heinrich Weber; JΓΌrgen Benz πŸ“‚ Article πŸ“… 1974 πŸ› John Wiley and Sons 🌐 English βš– 238 KB πŸ‘ 1 views

Extraction with ethyl acetate or ether and distillation of the crude furnishes pure (2). As shown in the reaction scheme, the overall reaction proceeds via several unisolated intermediates and it has not yet been established whether the cyclization occurs with (la) or ( 1 b). Remarkably, in the pres