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On the Mechanism of the Reductive Metallation of Asymmetrically Substituted Silyl Chlorides

✍ Scribed by Martin Oestreich; Gertrud Auer; Manfred Keller


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
258 KB
Volume
2005
Category
Article
ISSN
1434-193X

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Gencralizcd Hartrce-Fock (CHF) calculations Indicate that the aromatic substitutiou reaction kr the ground state CXI bc classified into three types: (A) nonradical ionic (S N2, SE2) reaction, where the closed-shell character is always retained; (B) electron-transfer type I (ET I) reaction, where the