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Concentrated salt effects on solvolysis rates in 1,4-dioxane–H2O mixed solvent and the expansion of the use of the Hammett equation for salt effects

✍ Scribed by Hojo, Masashi; Ueda, Tadaharu; Inoue, Sunao; Kawahara, Yuki

Book ID: 121480802
Publisher: Royal Society of Chemistry
Year: 2000
Tongue: English
Weight: 163 KB
Volume: 8
Category: Article
ISSN: 1472-779X
DOI: 10.1039/B001034K

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## Abstract Kinetic study on the cleavage of __N__‐phenylphthalimide (NPhPT) in the presence of 0.05 M NH~2~NH~2~ and mixed H~2~O‐CH~3~CN solvents reveals the occurrence of reaction scheme equation image where A, B, C, C~1~, An, E, and F represent NPhPT, __o__‐CO^−^~2~C~6~H~4~CONHC~6~H~5~, __o__‐