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β‘ ‘-(BEDT-TTF) 4 [(H 3 O)Cr(C 2 O 4 ) 3 ]CH 2 Cl 2 : Effect of Included Solvent on the Structure and Properties of a Conducting Molecular Charge-Transfer Salt

✍ Scribed by Rashid, Samina; Turner, Scott S.; Le Pevelen, Delphine; Day, Peter; Light, Mark E.; Hursthouse, Michael B.; Firth, Steven; Clark, Robin J. H.


Book ID
126159979
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
51 KB
Volume
40
Category
Article
ISSN
0020-1669

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New Molecular Charge Transfer Salts of B
✍ Scott S. Turner; Peter Day; Thomas Gelbrich; Michael B. Hursthouse 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 341 KB

Two new charge transfer salts of BEDT-TTF, bis (ethylenedithio) tetrathiafulvalene, with thiocyanato-metal complex anions have been synthesized and characterized as (BEDT-TTF) 4 [Fe(NCS) 6 ] ' CH 2 Cl 2 and (BEDT-TTF) 2 [Cr(NCS) 4 (bipym)] ' 0.15H 2 O, where bipym ‫؍‬ 2,2-bipyrimidine. The Fe salt,