Computational Study of Main Mechanisms for Gas-Phase Decomposition of 1,1- and 1,2-Dinitroethane
✍ Scribed by Tsyshevsky, Roman V.; Aristov, Ilia V.; Chachkov, Denis V.; Shamov, Alexander G.; Khrapkovskii, Grigorii M.
- Book ID
- 120500518
- Publisher
- Taylor and Francis Group
- Year
- 2010
- Tongue
- English
- Weight
- 805 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0737-0652
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The gas phase pyrolysis of 1,1,1,2-tetrachloropropane was studied in a ,static system and seasoned vessel over the temperature range of 393.0-452.8"C and pressure range of 27.5-1 18.5 torr. The reaction is homogeneous, unimolecular, follows a first-order rate law, and is not affected by the presence
## Abstract The cyclic sulfenic ester 1,2‐oxathiolane (**1**) decomposes thermally (400 – 450 K) exclusively to give acrolein (**3**) __via__ 3‐mercaptopropanal (**2**) by loss of hydrogen sulfide. Isotopic labelling experiments reveal the presence of a 1,2‐oxathiolane‐thietane 1‐oxide equilibrium