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Computational prediction of new mechanisms for the reactions of vinyl and phenyl radicals with molecular oxygen

✍ Scribed by Carpenter, Barry K.

Book ID
118255870
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
228 KB
Volume
115
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Kinetics and mechanism of the reaction o
Kinetics and mechanism of the reaction of vinyl radicals with molecular oxygen
✍ Jong-Yoon Park; Michael C. Heaven; David Gutman πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 English βš– 501 KB

The kinetics and mechanism of the gaseous reaction of vinyl radicals with molecular oxygen have been studied at 296 K. The products formed are HCO and H2C0. The rate constant is 1.0 X 10-r' cm3 molecule-' s-\* and is independent of pressure between 0.4 and 4 Torr.

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Pressure dependence of the phenylperoxy radical (C 6 H 5 O 2 ) formation in the reaction of phenyl radical (C 6 H 5 ) with molecular oxygen (O 2 ) has been investigated with the cavity ring-down method by detecting the C 6 H 5 O 2 at 504 nm. The rate constant of the C 6 H 5 + O 2 reaction was determ

The reactions of methyl radicals with at
The reactions of methyl radicals with atomic and molecular oxygen
✍ N. Washida; Kyle D. Bayes πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 English βš– 925 KB

## Abstract The reaction of methyl radicals with atomic and molecular oxygen was studied with a photoionization mass spectrometer. The methyl radicals were generated by reacting oxygen atoms with ethylene in a fast‐flow tube reactor. The rate constant for the reaction of methyl radicals with oxygen