Computational Study of the Reaction of Chlorinated Vinyl Radical with Molecular Oxygen (C 2 Cl 3 + O 2 )
โ Scribed by Wang, Huan; Li, Jicun; Song, Xinli; Li, Yuzhen; Hou, Hua; Wang, Baoshan; Su, Hongmei; Kong, Fanao
- Book ID
- 126335148
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 424 KB
- Volume
- 110
- Category
- Article
- ISSN
- 1089-5639
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The kinetics of the gas-phase reaction of C1 atoms with CF31 have been studied relative to the reaction of C1 atoms with CH4 over the temperature range 271-363 K. Using k(C1 + CH4) = 9.6 X exp(-2680/RT) cm3 molecule-' s-', we derive k(C1 + CF3I) = 6.25 X lo-'' exp(-2970/RT) in which E , has units of