Phosphirane sind dreigliedrige Ringe mit einem gespannten PC 2 -Gerüst, [1a, b] die als Liganden für homogene Übergangsmetallkatalysatorkomplexe interessant sein könnten. Ihre kleine Bindungswinkelsumme am Phosphorzentrum (Sa(P): 240 ± 275 8) sollte ihnen gute p-Acceptoreigenschaften verleihen, [1c]
✦ LIBER ✦
Complexes of Phosphirane
✍ Scribed by R. Bausch; Professor E. A. V. Ebsworth; Dr. D. W. H. Rankin
- Publisher
- John Wiley and Sons
- Year
- 1971
- Tongue
- English
- Weight
- 136 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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## 12 -163 A New Stereoselective Synthesis of Phosphiranes. -Both enantiomers of the phosphirane (III) and the corresponding meso-compound (IX) are prepared and converted to their tungsten pentacarbonyl and tungsten tetracarbonyl-triphenylphosphine complexes, e.g. (V) and (VII). In the case of the