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Complexes of hydroxamates III.: Equilibrium and kinetic studies on the reactions of iron(III) with monohydroxamic acids

✍ Scribed by Nadyah M. Shuaib; Hayat M. Marafie; Mansour M. Hassan; Mohamed S. El-Ezaby

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 748 KB
Volume: 31
Category: Article
ISSN: 0162-0134
DOI: 10.1016/0162-0134(87)80003-x

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The copper-catalyzed oxidation of hydrazine by iron(II1) in acid solution follows the rate law -d[Fe(III)]/dt = ~K~[CU(II)]~/(K~ + [H+]), where Kh is the hydrolysis constant of Cu2+, k was found t o be 8.8f0.8, 13.2f1.4 and 17.5f1.3 min-' at 35, 40, and 45OC respectively and p= 0.2 mol/L. The compos