A thermodynamic study of the complexation reaction for some amino acids with cerium(III) and yttrium(III)
β Scribed by B.S. Sekhon; S.L. Chopra
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 343 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0040-6031
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π SIMILAR VOLUMES
Complexation of aluminum ions {AI(III) in glycerol} with a-amino acids has been studied by FAB mass spectrometry. Twelve a-amino acids and cysteine methyl ester interact with different Al(II1)-containing ions and form several cluster ions such as [M+117]', [117={Al(LII)+glycerol-2H}]; [M+231]+, [231
Ξ· 5 -Pentamethylcyclopentadienyliridium(III) and -rhodiumΞΈ = 12.9Β°from that of the remaining ring atoms. Facial isomers are present in an effective 1:1 ratio for all tryptophan (III) sandwich complexes of the type [(Ξ· 5 -Cp\*)M(Ξ· 6 -aa)]-(CF 3 SO 3 ) 2 (M = Ir, Rh; 3-14) containing L-tyrosine, L-try