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Complexes of group IIb metals with dithiooxamides: I. Thermal properties of Zn(CH3NHCSCSNHCH3)X2 (X = Cl, Br, I) complexes

โœ Scribed by P. Geboes; E.L. Esmans; H.O. Desseyn


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
370 KB
Volume
124
Category
Article
ISSN
0040-6031

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Complexes of group IIb metals with dithi
โœ P. Geboes; H.O. Desseyn ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 461 KB

## With dithiooxamides, Zn(II) in acid media forms distorted tetrahedral complexes, which behave as non-electrolytes. The ligands act as bidentates with S, S coordination. A thorough vibrational analysis has been performed for the Zn(CH,NHCSCSNHCH,)X, (X =Cl, Br, I) and for the Zn[(CH,),NCSCSN(