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The nature of gas-phase complexes R3PHX (RH, CH3; XCl, Br, I)

✍ Scribed by Birgit Müller; Joachim Reinhold

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 259 KB
Volume: 196
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(92)85983-h

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## Abstract The reactions of small saturated hydrocarbons by gaseous nickel cations NiX^+^ (X=F, Cl, Br, I) are investigated by means of electrospray ionization mass spectrometry. The halide cations are obtained from solutions of the corresponding Ni^II^ salts in water or methanol as solvents. NiF^