Complexes of group IIb metals with dithio oxamides—II. Vibrational analysis of ZnLX2(X = Cl, Br, I) complexes

✍ Scribed by P. Geboes; H.O. Desseyn

• Publisher: Elsevier Science
• Year: 1988
• Tongue: English
• Weight: 461 KB
• Volume: 44
• Category: Article
• ISSN: 1386-1425
• DOI: 10.1016/0584-8539(88)80213-7

✦ Synopsis

With dithiooxamides,

Zn(II) in acid media forms distorted tetrahedral complexes, which behave as non-electrolytes.

The ligands act as bidentates with S, S coordination.

A thorough vibrational analysis has been performed for the Zn(CH,NHCSCSNHCH,)X, (X =Cl, Br, I)

and for the Zn[(CH,),NCSCSN(CH,),IX,(X=Cl, Br, I) complexes.

INTRODVCTION