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Complexation of nucleotides and molecular catalysis of ATP-hydrolysis by a protonated hexaaza macrocyclic ligand

✍ Scribed by Qin Lu; Arthur E. Martell; Ramunas J. Motekaitis


Book ID
108328418
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
539 KB
Volume
251
Category
Article
ISSN
0020-1693

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Efficient Molecular Catalysis of ATP-Hyd
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## Abstract Molecular catalysis of ATP‐hydrolysis by a number of protonated macrocyclic polyamines **1–9** has been investigated by ^31^P‐NMR spectroscopy, and marked rate enhancements have been obtained. The largest acceleration is produced by the [24]‐N~6~O~2~ macrocycle **1**, and the process di