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Catalysis of hydrolysis of a phosphate diester by mono- and dinuclear macrocyclic zinc(II) complexes

โœ Scribed by P Jurek; A.E Martell


Book ID
108331751
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
132 KB
Volume
287
Category
Article
ISSN
0020-1693

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Five components spontaneously self-assemble to yield the productive complex 1, where one barium ion delivers an ethoxide to the carbonyl group of an amide substrate anchored by means of a distal carboxylate moiety to the other barium ion. High substrate specificity, fairly high reaction rates with c