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Supramolecular Catalysis of Ester and Amide Cleavage by a Dinuclear Barium(II) Complex

✍ Scribed by Roberta Cacciapaglia; Stefano Di Stefano; Erik Kelderman; Luigi Mandolini

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 134 KB
Volume: 38
Category: Article
ISSN: 0044-8249
DOI: 10.1002/(sici)1521-3773(19990201)38:3<348::aid-anie348>3.0.co;2-d

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✦ Synopsis

Five components spontaneously self-assemble to yield the productive complex 1, where one barium ion delivers an ethoxide to the carbonyl group of an amide substrate anchored by means of a distal carboxylate moiety to the other barium ion. High substrate specificity, fairly high reaction rates with catalytic turnover, and competitive inhibition by inert substrates are observed.

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