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Gemini metallomicellar catalysis: Hydrolysis of p-nitrophenyl picolinate catalyzed by Cu(II) and Ni(II) complexes of macrocyclic ligands in gemini surfactant micelles

✍ Scribed by Ling-Guang Qiu; Xia Jiang; Li-Na Gu; Gang Hu

Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
207 KB
Volume
277
Category
Article
ISSN
1381-1169

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Metallomicelle catalysis: Hydrolysis of
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## Abstract Two Schiff base cobalt(II) complexes containing crowned substituents have been synthesized and employed to promote the hydrolysis of __p__‐nitrophenyl picolinate (PNPP) in a buffered micellar solution formed by a cationic Gemini surfactant, bis(hexadecyldimethylammonium)hexane bromide (

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The ternary complex kinetic model for metallomicellar catalysis has been proposed in this paper. The catalytic effects of bivalent metal ion (Cu(2+), Zn(2+), and Ni(2+)) complexes of long alkyl pyridine ligands upon the hydrolysis of p-nitrophenyl picolinate (PNPP) have been studied kinetically in a