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Complex kinetics in the bromate-iodide reaction: a clock reaction mechanism

✍ Scribed by Simoyi, Reuben H.; Masvikeni, Patricia; Sikosana, Angela

Book ID
120463382
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
748 KB
Volume
90
Category
Article
ISSN
0022-3654

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Temperature and pressure effects on the
Temperature and pressure effects on the kinetics of the Bromate ion-iodide ion-L-ascorbic acid clock reaction
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The kinetics of the bromate ion-iodide ion-L-ascorbic acid clock reaction was investigated as a function of temperature and pressure using stopped-flow techniques. Kinetic results were obtained for the uncatalyzed as well as for the Mo(V1) and V(V) catalyzed reactions. While molybdenum catalyzes the