Salt Effects in the Reaction between Bromate and Iodide Ions
β Scribed by Indelli, Antonio; Nolan, George; Amis, Edward S.
- Book ID
- 125977121
- Publisher
- American Chemical Society
- Year
- 1960
- Tongue
- English
- Weight
- 473 KB
- Volume
- 82
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
## Abstract The kinetic salt effect in the ^18^Oβexchange reaction between bromate ion and water has been investigated at 60Β° in a range of ionic strength from 0.02M < I < 1.9M using NaNO~3~ or NaClO~4~ as inert salts. From the experimental data the following relation was deduced for the uncatalyse
The kinetics of the bromate ion-iodide ion-L-ascorbic acid clock reaction was investigated as a function of temperature and pressure using stopped-flow techniques. Kinetic results were obtained for the uncatalyzed as well as for the Mo(V1) and V(V) catalyzed reactions. While molybdenum catalyzes the