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Complex formation between silver perchlorate and Azo-bis-isobutyronitrile

โœ Scribed by C.H Bamford; G.C Eastmond; J Hobbs; E Hughes

Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
193 KB
Volume
10
Category
Article
ISSN
0032-3861

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Luminescent bimetallic complexes. Study of the formation, redox behavior, and photochemistry of complexes between Ag+ and bis(2,2โ€ฒ-bipyridine)-bis-cyanoruthenium(II)
โœ Michael G. Kinnaird; David G. Whitten ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 470 KB

The complex, bis(2,2'-bipyridine)-bis-cyanoruthenium(II), (D), forms three detectable ground-state complexes with silver(I): DAg +, D2Ag +, and DAg~ +. The first, DAg รท, is isolable and strongly luminescent. Both DAg +\* and the oxidized complex, DAg 2+, are stable during photochemical experiments.