✦ LIBER ✦

Luminescent bimetallic complexes. Study of the formation, redox behavior, and photochemistry of complexes between Ag+ and bis(2,2′-bipyridine)-bis-cyanoruthenium(II)

✍ Scribed by Michael G. Kinnaird; David G. Whitten

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 470 KB
Volume: 88
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(82)87087-5

No coin nor oath required. For personal study only.

✦ Synopsis

The complex, bis(2,2'-bipyridine)-bis-cyanoruthenium(II), (D), forms three detectable ground-state complexes with silver(I): DAg +, D2Ag +, and DAg~ +. The first, DAg ÷, is isolable and strongly luminescent. Both DAg +* and the oxidized complex, DAg 2+, are stable during photochemical experiments. The enhanced luminescence of DAg ÷ indicates intramolecular redox reactions are not an important route for non-radiative decay.

📜 SIMILAR VOLUMES

Synthesis, Characterization and Luminesc

Synthesis, Characterization and Luminescence Properties of Dipyridin-2-ylamine Ligands and Their Bis(2,2′-bipyridyl)ruthenium(II) Complexes and Labelling Studies of Papain from Carica papaya

✍ Pierre Haquette; Julien Jacques; Samuel Dagorne; Céline Fosse; Michèle Salmain 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 665 KB

Ruthenium Complexes of Easily Accessible

Ruthenium Complexes of Easily Accessible Tridentate Ligands Based on the 2-Aryl-4,6-bis(2-pyridyl)-s-triazine Motif: Absorption Spectra, Luminescence Properties, and Redox Behavior

✍ Matthew I. J. Polson; Elaine A. Medlycott; Garry S. Hanan; Larisa Mikelsons; Nic 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 304 KB 👁 2 views

Synthesis, Redox Properties, and EPR Spe

Synthesis, Redox Properties, and EPR Spectroscopy of Manganese(III) Complexes of the Ligand N,N-Bis(2-hydroxybenzyl)-N′-2-hydroxybenzylidene-1,2-diaminoethane: Formation of Mononuclear, Dinuclear, and Even Higher Nuclearity Complexes

✍ Heimo Schmitt; Reiner Lomoth; Ann Magnuson; Jonathan Park; Jacob Fryxelius; Mika 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 232 KB 👁 2 views

Nature of the lowest energy excited stat

Nature of the lowest energy excited state of a bis-phenanthroline [2]-catenand and its Cu(I), Ag(I) and Co(II) complexes

✍ Nicola Armaroli; Michael A.J. Rodgers; Paola Ceroni; Vincenzo Balzani; Christine 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 286 KB

The excited state absorption and emission spectra and lifetimes of a [2]-catenand made of two interlocked 30-membered rings (containing 2,9-dianisyl-l,10-phenanthroline-type coordinating moieties) and its Co 2÷, Cu +, and Ag ÷ complexes have been investigated in CH2CI 2 solution. The lowest energy e

ChemInform Abstract: Synthesis, Spectros

ChemInform Abstract: Synthesis, Spectroscopic and a ZINDO Study of cis- and trans-(X2)Bis(4,4′-dicarboxylic acid-2,2′-bipyridine)ruthenium(II) Complexes (X: Cl-, H2O, NCS-)

✍ Md. K. Nazeeruddin; S. M. Zakeeruddin; R. Humphry-Baker; S. I. Gorelsky; A. B. P 📂 Article 📅 2000 🏛 John Wiley and Sons ⚖ 30 KB

Investigation of the Conformational Infl

Investigation of the Conformational Influences on the Estrogenic Activity of 1,2-Bis(2,6-dichloro-4-hydroxyphenyl)-ethylenediamines and of their Platinum(II) Complexes, II: Synthesis and Studies on the Estrogenic Activity of cis- and trans[Bis(2,6-dichloro-4-hydroxybenzylamine)]dihaloplatinum(II)-Complexes

✍ Ronald Gust; Helmut Schönenberger 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 538 KB