Effect of substituents on adduct formation between 4-picoline and various bis(O,O′-dialkyldithiophosphato) nickel(II) complexes

One-dimensional structures of nickel(II)

One-dimensional structures of nickel(II) and cobalt(II) coordination complexes {[ML2(H2O)2]·L·H2O·(ClO4)2} (M=Co or Ni; L=1,3-bis(4-pyridyl)propane)

✍ M John Plater; Mark R.St J Foreman; Thomas Gelbrich; Michael B Hursthouse 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 133 KB

Treatment of 1,3-bis(4-pyridyl)propane with Co(II)(ClO 4 ) 2 or Ni(II)(ClO 4 ) 2 gives isostructural one-dimensional coordination polymers. The metal ions have an octahedral geometry and are bridged by two crystallographically independent ligands along each chain. Alongside each coordination chain a