## Abstract In low dielectric solvents such as pyridine or isopropylamine, sodium perchlorate interacts strongly with a variety of sugars. The interaction is best described as non‐specific, with close proximity of the ionic partners maintained, as in a sugar‐shared ion pair.
Complex formation between iron(III) and thiosulfate in non-aqueous media.
✍ Scribed by D. Díaz; H. Morales-Rojas; A.K. Yatsimirsky
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 73 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0162-0134
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The kinetics of oxidation of thiosulfate to tetrathionate by trans-dihydroxotetraoxoosmate(VII1) in aqueous alkaline media have been studied. The oxidation follows a rate expression where K a is the formation constant of trans-dihydroxotetraoxoosmate (VIII), and K2 and ka, respectively, represent t
The electrochemical behaviour of tris /I-(dionato) iron (III) complexes (FeL,) was studied in an aprotic medium (DMF), in the presence of chloride ions. Additions of perchloric acid can promote a ligand exchange with formation of mixed chloro-complexes. The latter are unstable in a polar solvent suc
## Abstract The binding process between sodium poly(L‐glutamate) and __trans__‐2,2′,2″,2‴‐tetrapyridyl‐Fe(III) complex ions in aqueous solution at pH around 7 has been studied by means of equilibrium dialysis and optical measurements. The binding isotherm indicates the occurrence of a cooperative p