✦ LIBER ✦

Electrochemical reduction of chloro-bis(dionato) iron (III) complexes in non-aqueous medium

✍ Scribed by M. Lamrani; G. Mousset

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 379 KB
Volume: 38
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(93)80234-q

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✦ Synopsis

The electrochemical behaviour of tris /I-(dionato) iron (III) complexes (FeL,) was studied in an aprotic medium (DMF), in the presence of chloride ions. Additions of perchloric acid can promote a ligand exchange with formation of mixed chloro-complexes. The latter are unstable in a polar solvent such as DMF. The cyclic voltammograms show that FeCl; and the tris jI-(dionato) iron (III) complexes are formed by disproportionation of FeL,Cl.

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