Evidence of iron(III)-oxalato complex formation in aqueous solution from x-ray diffraction
β Scribed by Mauro Magini
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 563 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0009-2614
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The kinetics and mechanism of the reaction of complexation of iron(II1) with 2,4-octanedione and 2,4-nonanedione have been investigated spectrophotometrically in aqueous solution at 10Β°C and ionic strength 0.5 mol dm-3 NaC104. The equilibrium constants of the monocomplexes have been determined. The
## Abstract Despite the crucial role of βiron(III) citrate systemsβ in the iron metabolism of living organisms (bacteria as well as plants or mammals), the coordination chemistry of ferric citrate remains poorly defined. Variations in the experimental conditions used for the preparation of soβcalle