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Comparison of translational energy distributions calculated classically and quantally for the same reaction

✍ Scribed by L.K. Cohen; H.O. Pritchard

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 391 KB
Volume: 149
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)80379-8

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✦ Synopsis

Our earlier calculations of the unimolecular rate for the dissociation of N,O, performed both classically and quantally for the same potential model, have been extended so as to yield product translational energy distributions. Expectation values for the translational energy agree between the two methods, and the actual distributions also agree after allowance for the structure exhibited by the quanta1 solution.

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