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Classical trajectory calculation of the energy dependence of the total reaction cross section for K + CH3I → KI + CH3

✍ Scribed by R.A. Labudde; P.J. Kuntz; R.B. Bernstein; R.D. Levine

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
331 KB
Volume
19
Category
Article
ISSN
0009-2614

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✦ Synopsis

The translational energy (Lb) dependence of thkreaction cross section oR for K f RI * Ki f R (R = CII3) has been calculated (via clxsical trajectories) using a threcbody potential of the electron-jcmp type. Ihe m&mum irz the computed oR(E$,), attributed to recrossing from the ionic to covalent potential, is qlldit&iVdy simih to that found in the exper&n% of Gersh and Bernstein.

📜 SIMILAR VOLUMES

Observed translational energy dependence
Observed translational energy dependence of the K + C2H5I → KI + C2H5 reaction cross section from 0.17 to 0.55 eV (c.m.)
✍ F.J.L. Aoiz; V.J. Herrero; A.González Uren̄a 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 125 KB

Relatrve values of the total reactron cross section cR for the crossed molecular beam reactron K + C2H51 -\* KI + CaHs have been measured over the translational energy (ET) range 0 17-0.55 eV It IS found that OR decreases monotonically rrlth ET over thts range, any maximum tn oR(.!?T) is presumed to