Comparison of sheathless and sheath-flow electrospray interfaces for the capillary electrophoresis-electrospray ionization-mass spectrometry analysis of peptides
✍ Scribed by Victoria Sanz-Nebot; Elvira Balaguer; Fernando Benavente; José Barbosa
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 777 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0173-0835
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Capillary electrophoresis (CE) coupled to electrospray mass spectrometry via sheathless interfacing has been applied to the analysis of mammalian metallothionein (MT) extracts. In a rabbit-liver extract, four (MT-2C, MT-2A, MT-2D and MT-2E) out of six known MT sub-isoforms were unambiguously identif
Capillary zone electrophoresis (CZE) coupled with an on-line mass spectrometric (MS) detection system by an atmospheric pressure electrospray ionization (ESI) interface has been used successfully for separations of peptide and protein mixtures. For CZE-MS, ESI produces multiply charged molecular ion