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Comparison of crystal structures in the series [M(NH3)5NO2]XY and [M(NH3)5ONO]XY. Crystal structure of [Co(NH3)5NO2]I2

✍ Scribed by A. V. Virovets; N. V. Podberezskaya; E. V. Boldyreva; L. P. Burleva; S. A. Gromilov

Publisher
SP MAIK Nauka/Interperiodica
Year
1993
Tongue
English
Weight
547 KB
Volume
33
Category
Article
ISSN
0022-4766

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Study of the base-catalyzed nitrito–nitr
Study of the base-catalyzed nitrito–nitro isomerization reaction ([(NH3)5Co-ONO]2+ → [(NH3)5Co-NO2]2+) in mixed solvents
✍ R. Jiménez; M. Villar; M. Cueto; E. Grueso; J. Illanes; J. I. Cobrian; F. Cantón 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 88 KB

## Abstract The base‐catalyzed linkage isomerization of [Co(NH~3~)~5~‐ONO]^2+^ to the nitro [(NH~3~)~5~Co‐NO~2~]^2+^ form is studied in various isodielectric water–cosolvent mixtures (methanol, ethanol, __tert__‐butyl alcohol, and 2‐propanol) at 298 K. In all cases, except for methanol–water mixtur