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Comparative study of crystal structures in the series [M(NH3)5NO2XY and [M(NH3)5ONO]XY. crystal structure of [Co(NH3)5NO2]Cl·(NO3)

✍ Scribed by N. V. Podberezskaya; A. V. Virovets; E. V. Boldyreva

Publisher
SP MAIK Nauka/Interperiodica
Year
1992
Tongue
English
Weight
429 KB
Volume
32
Category
Article
ISSN
0022-4766

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Study of the base-catalyzed nitrito–nitro isomerization reaction ([(NH3)5Co-ONO]2+ → [(NH3)5Co-NO2]2+) in mixed solvents
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## Abstract The base‐catalyzed linkage isomerization of [Co(NH~3~)~5~‐ONO]^2+^ to the nitro [(NH~3~)~5~Co‐NO~2~]^2+^ form is studied in various isodielectric water–cosolvent mixtures (methanol, ethanol, __tert__‐butyl alcohol, and 2‐propanol) at 298 K. In all cases, except for methanol–water mixtur