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Comparative Kinetics and Mechanism of Oxygen and Sulfur Atom Transfer Reactions Mediated by Bis(dithiolene) Complexes of Molybdenum and Tungsten

✍ Scribed by Wang, Jun-Jieh; Kryatova, Olga P.; Rybak-Akimova, Elena V.; Holm, R. H.


Book ID
127168389
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
238 KB
Volume
43
Category
Article
ISSN
0020-1669

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✍ Hideki Sugimoto; Makoto Tarumizu; Hiroyuki Miyake; Hiroshi Tsukube πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 116 KB πŸ‘ 1 views

## Abstract Combined CEPT (coupled electron–proton transfer)/OAT (oxygen atom transfer) reactions were accomplished in (Bu~4~N)~2~[Mo^IV^O(bdtCl~2~)~2~] (1) and (Bu~4~N)~2~[Mo^VI^O~2~(bdtCl~2~)~2~] (2) complexes in aqueous media. The reaction mechanism of the CEPT reaction was analyzed electrochemi