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The reduction of tris-dithiolene complexes of molybdenum(vi) and tungsten(vi) by hydroxide ion: kinetics and mechanism

✍ Scribed by Cervilla, Antonio; P�rez-Pl�, Francisco; Llopis, Elisa; Piles, Mar�a

Book ID
117990024
Publisher
Royal Society of Chemistry
Year
2004
Tongue
English
Weight
180 KB
Volume
9
Category
Article
ISSN
1477-9226

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The different kinetic and mechanistic be
The different kinetic and mechanistic behaviors of molybdenum and tungsten in the reduction of tris(benzene-1,2-dithiolato)Mo(VI) and W(VI) complexes by ascorbic acid in aqueous media
✍ Francisco Pérez-Pla; Elisa Llopis; María Piles 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 386 KB

## Abstract The mono‐electronic reduction of __tris__(benzene‐1,2‐dithiolato)Mo(VI) and W(VI) complexes (ML~3~: M = Mo, W; L = S~2~C~6~H^2−^~4~, S~2~C~6~H~3~CH^2−^~3~) to their anionic forms ML^−^~3~ by L(+)‐ascorbic acid (H~2~A) has been studied in tetrahydrofurane (THF):water and THF:methanol by