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Kinetics of reduction of transition metal ions by sodium tetrahydroborate. Reduction of molybdenum(VI) and tungsten(VI)

โœ Scribed by Manash Dasgupta; Mahendra K. Mahanti

Publisher
Springer
Year
1988
Tongue
English
Weight
288 KB
Volume
13
Category
Article
ISSN
0340-4285

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## Abstract The monoโ€electronic reduction of __tris__(benzeneโ€1,2โ€dithiolato)Mo(VI) and W(VI) complexes (ML~3~: M = Mo, W; L = S~2~C~6~H^2โˆ’^~4~, S~2~C~6~H~3~CH^2โˆ’^~3~) to their anionic forms ML^โˆ’^~3~ by L(+)โ€ascorbic acid (H~2~A) has been studied in tetrahydrofurane (THF):water and THF:methanol by