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A Density Functional Study of Oxygen Atom Transfer Reactions between Biological Oxygen Atom Donors and Molybdenum(IV) Bis(dithiolene) Complexes

✍ Scribed by Thapper, Anders; Deeth, Robert J.; Nordlander, Ebbe


Book ID
111922414
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
147 KB
Volume
41
Category
Article
ISSN
0020-1669

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Bis(dithiolene) Molybdenum Complex that
✍ Hideki Sugimoto; Makoto Tarumizu; Hiroyuki Miyake; Hiroshi Tsukube πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 116 KB πŸ‘ 1 views

## Abstract Combined CEPT (coupled electron–proton transfer)/OAT (oxygen atom transfer) reactions were accomplished in (Bu~4~N)~2~[Mo^IV^O(bdtCl~2~)~2~] (1) and (Bu~4~N)~2~[Mo^VI^O~2~(bdtCl~2~)~2~] (2) complexes in aqueous media. The reaction mechanism of the CEPT reaction was analyzed electrochemi