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Computer Modeling of the Oxygen-atom Transfer Reaction between Hydrogen Sulfite and a Molybdenum(VI) Dioxo Complex

✍ Scribed by Thapper, Anders; Deeth, Robert J.; Nordlander, Ebbe

Book ID
127072629
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
57 KB
Volume
38
Category
Article
ISSN
0020-1669

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## Abstract Combined CEPT (coupled electron–proton transfer)/OAT (oxygen atom transfer) reactions were accomplished in (Bu~4~N)~2~[Mo^IV^O(bdtCl~2~)~2~] (1) and (Bu~4~N)~2~[Mo^VI^O~2~(bdtCl~2~)~2~] (2) complexes in aqueous media. The reaction mechanism of the CEPT reaction was analyzed electrochemi