Comment on “Determination of the rate constants of the reactions of N3 and NCl free radicals using a simulation technique”
✍ Scribed by Lawrence G. Piper
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 187 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0010-2180
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Rate constants for the reactions of 0, and OH radicals with acetylene, propyne, and 1-butyne have been determined at room temperature. The rate constants obtained a t 294 i 2 K for the reactions of 0, with acetylene, propyne, and 1-butyne were (7.8 -c 1.2) x lo-'' cm3/molecule . s, (1.43 2 0.15) x l
Using a relative rate method, rate constants for the gas-phase reactions of 2methyl-3-buten-2-ol (MBO) with OH radicals, ozone, NO 3 radicals, and Cl atoms have been investigated using FTIR. The measured values for MBO at and total 298 Ϯ 2 K 740 Ϯ 5 torr pressure are: Ϫ11 3 Ϫ1 Ϫ1 Ϫ18 3 k ϭ (3.9 Ϯ 1.
The rotating-sector method has been applied to the photoinitiated radical-chain decomposition of formamide at 300°C to measure the rate constant for the bimolecular disappearance of NH2 radicals. The decomposition is propagated by the reactions Conditions were chosen so that reaction (1) was rate c
An upper limit for the reaction rate of CO with the nitrate radical NO, has been determined equal to 4 x lo-'' cmt3 molec-' s-' a t 295 ? 2 K. In the experiment the isotopic species C13016 and C13018 mixed at 1-2 ppmv level in synthetic air have been reacted with NO3 and the reaction followed using