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Combined Spectroscopic and Computational Analysis of the Vibrational Properties of Vitamin B 12 in its Co 3+ , Co 2+ , and Co 1+ Oxidation States

✍ Scribed by Park, Kiyoung; Brunold, Thomas C.


Book ID
120018343
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
892 KB
Volume
117
Category
Article
ISSN
0022-3654

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Vibrational spectroscopic investigation
✍ Christopher E. Anson; Upali A. Jayasooriya πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 English βš– 645 KB

A detailed assignment of the v(C0) region of [Os,(CO),,] and [Ru~(CO),~] in the solid state is obtained by using relative intensities of these vibrational modes in the i.r. and Raman spectra. A qualitative intensity prediction is possible by recognizing that the real crystal structure of these solid