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Combined cycloalumination of cyclic 1,2-dienes and olefins with EtAlCl2 in the presence of Cp2ZrCl2 catalyst

✍ Scribed by Vladimir A. D’yakonov; Rustam K. Timerkhanov; Tatiana V. Tumkina; Natal’ya R. Popod’ko; Askhat G. Ibragimov; Usein M. Dzhemilev

Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
184 KB
Volume
50
Category
Article
ISSN
0040-4039

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✦ Synopsis

Catalytic intermolecular cycloalumination of cyclo-1,2-dienes and olefins assisted by EtAlCl 2 in the presence of Cp 2 ZrCl 2 as catalyst gave rise to unsaturated di-and polycyclic aluminacarbocycles.

📜 SIMILAR VOLUMES

Mechanism of Olefin Cycloalumination wit
Mechanism of Olefin Cycloalumination with Triethylaluminum into Aluminacyclopentanes Using Cp2ZrCl2 as a Catalyst
✍ Leonard M. Khalilov; Ludmila V. Parfenova; Sergey V. Rusakov; Aleksandr V. Balae 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 11 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Kinetic model of olefin hydroalumination
Kinetic model of olefin hydroalumination by HAlBui2 and AlBui3 in the presence of Cp2ZrCl2 catalyst
✍ Lyudmila V. Parfenova; Alexandr V. Balaev; Irek M. Gubaidullin; Liya R. Abzalilo 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 213 KB

## Abstract The mechanism of α‐olefin hydroalumination by HAlBu^__i__^~2~, ClAlBu^__i__^~2~, and AlBu^__i__^~3~ in the presence of Cp~2~ZrCl~2~ catalyst has been studied. It was established that the key intermediate of the reaction is a bimetallic complex [Cp~2~ZrH~2~ · ClAlBu^__i__^~2~]~2~, which