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Synthesis and transformations of metallacycles 33. The first example of cycloalumination of cyclonona-1,2-diene with Et3Al and EtAlCl2in the presence of Cp2ZrCl2

✍ Scribed by V. A. D’yakonov; R. K. Timerkhanov; A. G. Ibragimov; U. M. Dzhemilev


Publisher
Springer
Year
2007
Tongue
English
Weight
318 KB
Volume
56
Category
Article
ISSN
1573-9171

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Combined cycloalumination of cyclic 1,2-
✍ Vladimir A. D’yakonov; Rustam K. Timerkhanov; Tatiana V. Tumkina; Natal’ya R. Po 📂 Article 📅 2009 🏛 Elsevier Science 🌐 French ⚖ 184 KB

Catalytic intermolecular cycloalumination of cyclo-1,2-dienes and olefins assisted by EtAlCl 2 in the presence of Cp 2 ZrCl 2 as catalyst gave rise to unsaturated di-and polycyclic aluminacarbocycles.