The reactions between F2 and the lowest members of the homologous series of perfluoroalkyl iodides (CF31. C2F51. and n-C3F71) have been studied. For these compounds, an exponential decrease in the alkyl iodide concentration over time following an induction period is observed for certain experimental
Collisional enhancement of the I(52P12) emission at 1.3μm by parent molecules CF3I, C2F5I, i-C3F7I and n-C3F7I
✍ Scribed by Edgardo Gerck
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 348 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0030-4018
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The technique of laser photolysis of alkyl and perfluoroalkyl iodides at 266 nm followed by time-resolved detection of the 1.3-pm emission from I\*('PLI2) has been used to measure the rate constants for deactivation of I\* by CH31, C'HJ, CF31, and CH,. The recommended values are (2.76 2 0.22) x (2.
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