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Collision-induced dissociation of glycoside–alkali metal adduct ions in fast atom bombardment mass spectrometry

✍ Scribed by Mitsuo Takayama

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
390 KB
Volume
28
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

The collision‐induced dissociation (CID) spectra of glycoside–alkali metal adduct ions [M + C]^+^ (C = Li, Na, K and Rb) produced under fast atom bombardment (FAB) conditions are reported. The results obtained suggested that the CID spectra of the [M + C]^+^ ions of some flavonoid glycosides reflect the coordination structures because the CID patterns generally changed with the metal cation size. In diglycosides, the CID spectra showed that the relatively small cations Li^+^ and Na^+^ rather bind to the sugar moiety, whereas the large cations K^+^ and Rb^+^ rather bind to the aglycone moiety. In monoglycosides, the cations C^+^ rather bind to the aglycone moiety. It was concluded that the CID technique combined with FAB is useful for the structural elucidation of [M + C]^+^ ions and, in principle, the CID spectra reflect the coordination structures in the gas phase.

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