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Collision-induced Decomposition of Nitrobenzyl Alcohol-derived Ions Under Fast Atom Bombardment

✍ Scribed by Madhusudanan, K. P.

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
464 KB
Volume
31
Category
Article
ISSN
1076-5174

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✦ Synopsis

The collision-induced decomposition mass spectrum of protonated rn-nitrobenzyl alcohol (NBA) was studied. The various cluster ions fragment mainly by loss of neutral NBA. Nitro-to-nitrite isomerization followed by loss of 'NO is a favoured fragmentation pathway of the [MH]+ ion. Eliminations of *OH, H,O and HNO, are among the other common fragmentation routes. Alkali metal cationization also leads to prominent loss of 'NO. Accurate mass measurements and various linked scanning measurements were used to elucidate the fragmentation pathways.

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