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Collection of enantiomeric separation factors obtained by capillary gas chromatography on chiral stationary phases

✍ Scribed by König, W. A.


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
549 KB
Volume
16
Category
Article
ISSN
0935-6304

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## Heptakis(2,6-di-O-met hyl-3-O-pentyl)-~-cyclodextrin Structure Compound Column Temperaa Value name length [ml ture [ "C] a-Pinene 50 FS 70 1.057 50 % P-Pinene 50 FS 70 1.021 50 % Limonene 0 25 FS 50 % 70 1.070 h Camphene 50 FS 70 1.087 50 % Sabinene 50 FS 70 1.119 50 % Q a-Thujene 50 FS 50 % 70

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New chiral stationary phases of polydimethylsiloxane anchored with (S)-(À)-t-leucine derivatives were provided for use in enantiomer separation of pharmaceuticals by capillary gas chromatography. Fifteen pharmaceuticals were separated into their enantiomeric pairs by converting them into pentafluoro