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Collection of enantiomer separation factors obtained by capillary gas chromatography on chiral stationary phases


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
485 KB
Volume
16
Category
Article
ISSN
0935-6304

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✦ Synopsis


Heptakis(2,6-di-O-met hyl-3-O-pentyl)-~-cyclodextrin

Structure Compound Column Temperaa Value name length [ml ture [ "C] a-Pinene 50 FS 70 1.057 50 % P-Pinene 50 FS 70 1.021 50 % Limonene 0 25 FS 50 % 70 1.070 h Camphene 50 FS 70 1.087 50 % Sabinene 50 FS 70 1.119 50 % Q a-Thujene 50 FS 50 % 70 1.053 Ectocarpene 25 FS 70 1.022 50 % Desmarestene 25 FS 50 % 70 1016 h a-Copaene 25 FS 100 1.094 50 % (E)-a-Bisabolene 25 FS 85 1.037 50 % 25 FS 50 % 85 1.018 2-Phenylbutane 25 FS 70 1.040 50 % 6-n-Butyl-l,4-~ycloheptadiene, Dictyotene 0 -50 FS 50 % 90 1.025 1,2-Cyclononadiene** 25 FS T.P.


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fungal strains Tolypocladium inflatum, T. geodes, and T. terricola, which differ only by their N-acylpipecolic acid terminus). According to the primary amino acids found (1 Gly, 1 p-Ala, 1 L-Ala, 2 L-Leu and about 9 a-aminoisobutyric acid), it can be concluded, that tolypin represents a mixture of p