Coligand tuning of the DNA binding properties of bioorganometallic (??6-arene)ruthenium(ii) complexes of the type [(??6-arene)Ru(amino acid)(dppz)]n+??(dppz = dipyrido[3,2-a:2???,3???-c]phenazine), n??= 1???3
✍ Scribed by Frodl, Andr??; Herebian, Diran; Sheldrick, William S.
- Book ID
- 121418759
- Publisher
- The Royal Society of Chemistry
- Year
- 2002
- Tongue
- English
- Weight
- 322 KB
- Volume
- 19
- Category
- Article
- ISSN
- 1472-7773
- DOI
- 10.1039/B203569N
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## Abstract A novel polypyridine ligand, dipyrido[3,2‐__a:__2′,3′‐__c__]phenazine‐11‐carboxylic acid methyl ester (=dppz‐11‐CO~2~Me), and its ruthenium(II) complex, [Ru(bpy)~2~(dppz‐11‐CO~2~Me)]^2+^ (**1**), were synthesized and characterized. The binding properties of this complex to calf‐thymus D
## Abstract Two novel tridentate ruthenium(II) complexes containing an asymmetric heteroaromatic and a polyamine ligand, [Ru(dipn)(dptp)](ClO~4~)~2~ (**1**⋅2 $\rm{ ClO\_4^ -}$) and [Ru(dipn)(pat)](ClO~4~)~2~ (**2**⋅2 $\rm{ ClO\_4^ -}$) (dipn=__N__‐(3‐aminopropyl)propane‐1,3‐diamine; dptp=2‐(5,6‐dip