Water-swellable chelated polymers were synthesized, starting either from (1) In(III) or In(III) and Sn(II) as central ions and N-trimethoxysilylpropylethylenediamine or ethylenediamine each together with ethylenediaminetetraacetic acid (EDTA) as coordination ligands, or from (2) Ag(I) as the central ion and ethylene glycol (EG) and EDTA as coordination ligands, as follows: The nitrate(s) of the above metal ions together with the corresponding ligands were dissolved in water, and the solution was concentrated by heating to carry out the chelating polymerization. After cooling, the polymer was dried and ground to a fine powder, which was then mixed with a metal oxide powder by grinding in the presence of a small amount of water. A paste was thus obtained, which, after drying, was calcined at 200ΠC and subsequently at 750ΠC. The polymer became a sticky gel at 200ΠC, which adhered to the surface of the metal oxide particles; it was converted to an inorganic coating, In 2 O 3 {SnO 2 {SiO 2 , In 2 O 3 {SnO 2 , SnO 2 , or Ag, during the subsequent calcination at 750ΠC. Two metal oxide powders, namely, the electrically conductive In 2 O 3 and the nonconductive SnO 2 , were used as substrates. Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) indicated that the substrate particles were coated after calcination by a multicomponent oxide or silver layer. Temperature-resistant electrically antistatic film could be prepared by using the metal oxide coated In 2 O 3 particles as pigments and polypropylsiloxane as the binder. The Ag-coated SnO 2 powder had a conductivity s Γ
1.0 1 10 03 S cm 01 at 8.6 vol % Ag, while the mechanically mixed powders of Ag and SnO 2 exhibited a conductivity of 2.0 1 10 07 S cm 01 at 16 vol %.