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Co2(CO)8-catalyzed carbonylation of acetals using N-silylamines

โœ Scribed by Yoshihisa Watanabe; Kazuhiro Nishiyama; Fumio Okuda; Teruyuki Kondo


Publisher
Elsevier Science
Year
1992
Weight
531 KB
Volume
71
Category
Article
ISSN
0304-5102

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Selective 1,4-reduction of unsaturated c
โœ Hee-Yoon Lee; Mihyun An ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 384 KB

Unsaturated ketones and aldehydes were selectively reduced to the corresponding saturated carbonyl compounds by Co 2 (CO) 8 -H 2 O system. The current reducing system also offered a chemoselective reduction of less substituted unsaturated carbonyl groups.