Values of average energy transferred, (AC). and average energy loss, (h),, per collision were calculated from classical trajectories for collinear A\*+ M collisions in which A2 is highly vibrationally excited. Results were compared with those from the singleencounter impulsive collision model, from
Classical theory of vibration energy transfer in collinear collisions
✍ Scribed by H. Skenderović; S. Danko Bosanac
- Publisher
- Springer
- Year
- 1995
- Tongue
- English
- Weight
- 975 KB
- Volume
- 35
- Category
- Article
- ISSN
- 1434-6060
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📜 SIMILAR VOLUMES
An approlimatc approach is dcvelopcd to study the interfcrcncc of one-and twoquantum processes in collinear collisions of an atom and a harmonic oscillator. !n deriving an esplicit espression for vibrational transition probabilities, oncquantum processes arc trcatcd rigorously. while the contributio
Vibration-t~v~ration energy transfer rates for collision between two CO molecules arc calculated. Rcsul~ obtained are compared with recent experiments and theoretical valtys. it is pointed out that none of the existing wIcuIatians gives a complete clccount of the available experimental data.
WC have appl~tl Pcchukas aEd Mclafterty'i tclt for the cxactnoss of classical transItion state theory (TST) to t[lc cnllrncar subsurface of Porter and Karplus' H3 hypcrsurface and have detcrmmcd that TS r is c\act to at lca~t o.0592131 cv above the saddle point energy.